QUANTITATIVE DETERMINATION OF TRACE METALS AND SULPHUR CONTENT IN NIGERIAN PETROLEUM PRODUCTS USING AAS AND GRAVIMETRIC ANALYSIS TECHNIQUE, A RESEARCH PROJECT TOPIC ON PETROLEUM ENGINEERING

0
642

QUANTITATIVE DETERMINATION OF TRACE METALS AND SULPHUR CONTENT IN NIGERIAN PETROLEUM PRODUCTS USING AAS AND GRAVIMETRIC ANALYSIS TECHNIQUE, A RESEARCH PROJECT TOPIC ON PETROLEUM ENGINEERING

 

ABSTRACT

Eighteen trace heavy metals were quantitatively analyzed using atomic absorption spectroscopy; five samples of petroleum products were collected from Kaduna Refining and Petrochemical Company. Three different preparation methods were adopted for the determination of trace and heavy metals present in the various petroleum products viz: Direct sample aspiration into the flame after solvent dilution, Total acid (wet) digestion of the sample, Ashing of the sample and dissolution with an appropriate acid. Sample treatment with organic acid prior to aspiration proved to be more reliable and it gave good results for trace and heavy metals in petroleum products except for kerosene sample, where most of the elements responded positively to ashing preparation method. The level of eighteen elements analyzed in Petrol (PMS), Kerosene (DPK), Gas Oil (AGO), LPFO and Residual fuel are shown in table 3.7 which revealed that Potassium(120 mg/l, 340 mg/l, 120 mg/l, 2900 mg/l, 2050 mg/l) and Sodium (260 mg/l, 180 mg/l, 160 mg/l, 1800 mg/l, 1200 mg/l) are the most abundant elements in both the five sample under study followed by Iron(1.20 mg/l, 1.74 mg/l, 1.25 mg/l, 0.60 mg/l), Manganese(1.28 mg/l, 1.04 mg/l, 1.46 mg/l, 6.6 mg/l4.8 mg/l), Lead(0.50 mg/l, 0.16 mg/l, 0.40 mg/l, 27.8 mg/l, 24.6 mg/l) and Aluminium (0.42 mg/l, 1.06 mg/l, 0.32 mg/l, 0.82 mg/l, 24.6 mg/l). The concentration ranges of trace heavy metals analyzed are within the permissible levels set by World Health Organisation.

CHAPTER ONE

INTRODUCTION AND LITERATURE REVIEW

1.1        Introduction

Crude oil contains mainly hydrocarbons especially alkanes, naphthenes, and aromatics (Odebunmi and Adeniyi,2004),It contains also some nitrogen, oxygen and sulphur containing compounds along with trace amounts of elements especially nickel, vanadium, titanium, iron, cadmium etc(Odebunmi and Adeniyi,2004; Olajire and Oderinde,1996). The presence of trace metals and non-metals in the crude oil and petroleum products is destructive, especially in the refining process(Oderinde, 1989).Indigenous petroleum refineries, petroleum depots and filling stations as well as environment in general require enough information on the concentration of trace and heavy metals in Nigerian petroleum products because of its detrimental effects on both equipment and environment.

 

DOWNLOAD COMPLETE PROJECT MATERIAL

QUANTITATIVE DETERMINATION OF TRACE METALS AND SULPHUR CONTENT IN NIGERIAN PETROLEUM PRODUCTS USING AAS AND GRAVIMETRIC ANALYSIS TECHNIQUE, A RESEARCH PROJECT TOPIC ON PETROLEUM ENGINEERING

Leave a Reply